Re: [徵求] 物理高手 大一普物解題

看板San-Ying (三鶯)作者 (~馬克杯杯~)時間14年前 (2011/11/29 01:59), 編輯推噓5(504)
留言9則, 7人參與, 最新討論串3/3 (看更多)
路過手癢,答案作法不保證正確 請自行查證~謝謝!歡迎板友不吝指教! 就到第 7題,我欠一堆讀書債沒還 剩下請其他板友協助 1.http://ppt.cc/zkJj 0→75 Celsius degree L'=(1+0.0012)L ∵(1+ε)^3≒1+3ε ∴V'=(1+0.0012*3)V D =M/V →D'=M/V'=M/(1+0.0012*3)V≒(1-0.0012*3)D →0.36% 2.http://ppt.cc/Ddfw (a)0→40min △H=0.569*3031*(290-280)=K*40 ∴Absorption rate(K)=0.569*3031*0.25 J/min Fusion energy(K_f) 0.569*K_f=K*30,K_f=22732.5 J/kg (b)70→90min Specific heat(frozen phase)=S_f △H=K*20=0.569*(280-260)*S_f S_f=757.75 J/kg.K 3.http://ppt.cc/fGmH Vaporation heat of water=539 Cal/g Environment transfer is negletabl; thus have the following: △H=380*(T-100)*0.0923 =120*(100-20)*0.0923+ 120*(100-20)*1+ 539*7.26 copper bowl water For water :120*(100-20)*1+ 539*7.26=13513.14 For copper bowl:120*(100-20)*0.0923 =886.08 T=511 Celsius degree 4.http://ppt.cc/MPFR Application of law of thermodynamics △E=△Q- △W=△Q'- △W' (a)Path iaf=Path ibf →50.5- 21.4=37.0- W' W'=7.9 Cal (b)Path fi=-(Path iaf)→For the opposite direction ∴-(50.5- 21.4)=14.2+ Q' Q'=-43.3 Cal (c)E_int(f)- E_int(i)=Q- W →First law! ∴E_int(f)=E_int(i)+ Q- W=40.5 Cal (d)E_int(b)=22.5 @For path ib, it an iso-pressure procedure All energy is used as W(△E=0), Q_ib=W_ib=11.1 @For path bf, it an iso-volume procedure All energy is turned to be internal energy, Q_bf=E_bf=18.0 5.http://ppt.cc/CcUO nRT For isothermal process △E=0, P=----- V ╭ 0.31 ╭0.31 nRT 0.31 ∴W=△Q=│ PdV=│ -----dV=nRT.ln(----------) ╯ 0.31*2/3 ╯0.31*2/3 V 0.31*2/3 6 1280*---=0.9*8.314*0.4054*T →T=351.6 K 5 6.http://ppt.cc/6~yO Application of law of thermodynamics △E=△Q- △W=△Q'- △W' (a)23.3=△E+ P△V=△E+ (1.1*1.01*10^5)*(25*10^-6) For 1 atm=1.01*10^5 Nt/m^2 →△E=23.3- 2.7775=20.5 J (b)n=3.8*10^-3 mol @Constant P, △Q=△E+ P△V=△E+ nR△T 2.7775= (3.8*10^-3)*8.314*△T, △T=87.9 23.3 ∴C_p=-------------------=69.8 J/mol.K 87.9*(3.8*10^-3) @Constant V, △Q=△E ∴C_v=69.8- 8.314=61.5 J/mol.K 7.http://ppt.cc/LuIf dW= dQ- dE 3 →dW= TdS-(---nR)dT 2 7 2 According to the figure: T=---T_s- ---S 6 3 7 2 3 →dW=(---T_s- ---S)dS-(---nR)dT 6 3 2 ╭13.9 7 2 ╭449 3 →W=│ (---T_s- ---S)dS-│ (---nR)dT ╯1/4*13.9 6 3 ╯1/2*449 2 →W=-1095 J -- ※ 發信站: 批踢踢實業坊(ptt.cc) ◆ From: 114.34.109.77

11/29 02:42, , 1F
神人推
11/29 02:42, 1F

11/29 04:32, , 2F
看題目就覺得頭暈= =
11/29 04:32, 2F

11/29 10:31, , 3F
完全看不懂QQ
11/29 10:31, 3F

11/29 11:12, , 4F
第四題有物唷! 熱力學第一定律是U2-U1=Q-W
11/29 11:12, 4F

11/29 12:53, , 5F
感激不盡!!
11/29 12:53, 5F

11/29 20:14, , 6F
樓主的整個熱力學公式都錯囉! 後面幾題也需要做更正唷!
11/29 20:14, 6F

11/29 21:23, , 7F
還請樓上指正~太久沒有接觸(汗)
11/29 21:23, 7F

11/29 21:46, , 8F
不敢不敢! 小弟最近剛好準備研究所的材熱所以才較熟而已xd
11/29 21:46, 8F
※ 編輯: modernage 來自: 114.32.115.221 (11/29 23:57)

11/30 15:29, , 9F
恩 跟我想得差不多
11/30 15:29, 9F
文章代碼(AID): #1Eqylf_Y (San-Ying)
文章代碼(AID): #1Eqylf_Y (San-Ying)